Chemistry 401

Intermediate Inorganic Chemistry

University of Rhode Island

Lectures

Fall 2008

Date

September 3, 2008

September 5, 2008

September 8, 2008

September 10, 2008

September 12, 2008

September 15, 2008

September 17, 2008

September 19, 2008

September 22, 2008

September 24, 2008

September 26, 2008

September 29, 2008

October 1, 2008

October 6, 2008

October 8, 2008

October 10, 2008

October 15, 2008

October 17, 2008

October 20, 2008

October 22, 2008

October 24, 2008

October 27, 2008

October 29, 2008

November 3, 2008

November 5, 2008

November 7, 2008

November 10, 2008

November 14, 2008

November 17, 2008

November 19, 2008

November 21, 2008

November 24, 2008

November 26, 2008

December 1, 2008

December 3, 2008

December 8, 2008

Lecture Topic

Course Introduction, Atomic Structure

Hydrogenic Wavefunctions

Electron Configurations and Terms Symbols

Z* and Periodic Properties

Lewis Structures

Valence Shell Electron Pair Repulsion Model

More VSEPR; hybridization

Molecular Orbital Theory; Linear Combination of Atomic Orbitals

MO diagrams for homonuclear diatomics

MO diagrams for heteronuclear diatomics

MO diagrams for polyatomic molecules

Solid State Structure

Energetics of Ionic Solids

Born Haber Cycles

Metallic Bonding

Semiconductors

Introduction to Brønsted-Lowry Acid/Base Theory

Structural aspects of Brønsted-Lowry Acids and Bases

Introduction to Lewis Acid/Base Theory

Thermodynamic Aspects of Lewis Acid/Base Reactions

Introduction to Oxidation/Reduction Reactions; Thermodynamics

Methods of Reporting Reduction Potentials

Kinetic Aspects of Oxidation/Reduction Reactions

Physical Techniques Used in Inorganic Chemistry

Symmetry and Point Groups

Introduction to Transition Metal Chemistry

Ligands

Nomenclature of Transition Metal Compounds

Crystal Field Theory

Influences on the size of Dq; Measuring Spin State; Measuring Dq

Thermodynamics of Transition Metal Complexes; Nonoctahedral Geometries; Jahn-Teller Effect

Valence Bond Theory for Transition Metal Complexes

Molecular Orbital Theory for Transition Metal Complexes

Reactions of Transition Metal Complexes

Reactions of Organometallic Compounds; Metal-Metal Bonds and Clusters

Review for the Final Exam