CHM 501 Lecture

Weak Interactions

These types of forces are responsible for formation of liquids and solids in covalently bonded species.

Ion-dipole coulombic attraction; usually a cation with a dipole

E = energy Z = ion charge = dipole moment 0 = permittivity of free space

r = distance between ion and center of the dipole

Dipole-dipole requires either a molecular dipole or a bond dipole

directional, shorter range

Ion-Induced Dipole

is the polarizability of the neutral

Dipole-Induced Dipole



Instantaneous Dipole-Induced Dipole (van der Waal’s or London Dispersion)

IP = ionization potential

van der Waal’s interaction explain the condensation of nonpolars:
halogen
bp (oC, 1 atm)
n-alkane
bp (oC, 1 atm)
F2
-187
CH4
-161
Cl2
-35
C2H6
-88
Br2
59
C3H8
-42
I2
183 (extrapolated)
C4H10
-1
   
C8H18
125